- Abstract:
-
The underlying electron-transfer and coupled chemical processes associated with biologically important catalytic reactions can be resolved using a combination of Fourier transform ac voltammetry with an analysis of the separated dc and ac components. This outcome can be achieved because the response associated with generation of the catalytic current is essentially confined to the steady-state dc component, whereas the electron-transfer step is dominant in the fundamental and higher harmonics...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ac048151y
-
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- Journal:
- Analytical chemistry
- Volume:
- 77
- Issue:
- 11
- Pages:
- 3502-3510
- Publication date:
- 2005-06-05
- DOI:
- EISSN:
-
1520-6882
- ISSN:
-
0003-2700
- URN:
-
uuid:4a24e9f8-8077-4d29-951c-620602c97721
- Source identifiers:
-
39485
- Local pid:
- pubs:39485
- Copyright date:
- 2005
Journal article
Separation of electron-transfer and coupled chemical reaction components of biocatalytic processes using Fourier transform ac voltammetry.
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