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Journal article

Structural and near-IR photophysical studies on ternary lanthanide complexes containing poly(pyrazolyl)borate and 1,3-diketonate ligands.

Abstract:

The ligands tris[3-(2-pyridyl)pyrazol-1-yl]hydroborate (L1, potentially hexadentate) and bis[3-(2-pyridyl)pyrazol-1-yl]dihydroborate (L2, potentially tetradentate) have been used to prepare ternary lanthanide complexes in which the remaining ligands are dibenzoylmethane anions (dbm). [Eu(L1)(dbm)2] is eight-coordinate, with L1 acting only as a tetradentate chelate (with one potentially bidentate arm pendant) and two bidentate dbm ligands. [Nd(L1)(dbm)2] was also prepared but on recrystallizat...

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Publication status:
Published

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Publisher copy:
10.1039/b400992d

Authors


Davies, GM More by this author
Aarons, RJ More by this author
Motson, GR More by this author
Jeffery, JC More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
8
Pages:
1136-1144
Publication date:
2004-04-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:49b7f141-ca02-4e0a-b982-ed1260b1adf6
Source identifiers:
46798
Local pid:
pubs:46798
Language:
English

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