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Selective anion-exchange properties of second-stage layered double hydroxide heterostructures

Abstract:

The anion-exchange properties of second-stage [Zn2Cr(OH) 6]Cl0.5(succinate)0.25·nH2O (Zn2Cr-Succ/Cl) and [Zn2Cr(OH)6]Cl 0.5(tartrate)0.25·nH2O (Zn 2Cr-Tart/Cl) materials were investigated by means of time-resolved in situ energy-dispersive X-ray diffraction (EDXRD). Selective anion-exchange reactions were observed that were a result of the segregation between organic and inorganic anions. Indeed, the reaction of Zn2Cr-Succ/Cl and Zn2Cr-Tart/Cl second-stage compounds with either fluoride or ad...

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Publication status:
Published

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Publisher copy:
10.1021/cm0605825

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
CHEMISTRY OF MATERIALS
Volume:
18
Issue:
18
Pages:
4312-4318
Publication date:
2006-09-05
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
URN:
uuid:4990fe2e-0551-4d7e-8751-384195f892fd
Source identifiers:
51288
Local pid:
pubs:51288
Language:
English

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