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Kinetic study of the intercalation of cobaltocene by layered metal dichalcogenides with time-resolved in situ X-ray powder diffraction

Abstract:

Energy-dispersive X-ray diffraction (EDXRD) has been used to perform in situ kinetic studies on the intercalation of cobaltocene, Co(η-C5H5)2, into the layered dichalcogenides ZrS2, 2H-SnS2, 2H-SnSe2, 2H-TaS2, 2H- NbS2, 1T-TaS2, and TiS2. Integrated intensities of the Bragg reflections have been used to determine the extent of reaction (α) versus time for each of these reactions. The half-lives (t(1/2)) for reaction of an excess of cobaltocene with ZrS2, 2H-SnS2, 2H-SnSe2, 2H-TaS2, 2H-NbSe2, ...

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Publication status:
Published

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Publisher copy:
10.1021/ja9819099

Authors


Evans, JSO More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume:
120
Issue:
42
Pages:
10837-10846
Publication date:
1998-10-28
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:49688fb6-6525-4e53-90c5-94daa300bfa8
Source identifiers:
51138
Local pid:
pubs:51138
Language:
English

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