Two Vernier-templated routes to a 24-porphyrin nanoring.
- Many hands make light work: Small templates working together have directed the formation of a giant π-conjugated macrocycle with a diameter of 10 nm-larger than many enzymes. The 24 porphyrin subunits of the nanoring are well resolved in the STM image. The conformation of the nanoring can be controlled by self-assembly of a stable 2:24 double-strand sandwich complex with 1,4-diazabicyclo[2.2.2]octane (DABCO). Copyright © 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
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