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Synthesis of early transition metal carbides and their application for the reforming of methane to synthesis gas

Abstract:

Binary and ternary group V and VI transition metal oxides were converted to their carbides using temperature programmed reduction (TPR). When ethane was substituted for methane in the TPR, transmission electron microscopy indicated that the oxide-carbide transformation proceeded topotactically. The carbides synthesised were tested as catalysts for methane reforming with carbon dioxide (dry reforming), giving carbon monoxide and hydrogen (synthesis gas) as the main products; of the binary carb...

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Authors


Claridge, JB More by this author
Márquez-Alvarez, C More by this author
Brungs, AJ More by this author
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Journal:
Studies in Surface Science and Catalysis
Volume:
110
Pages:
711-720
Publication date:
1997
ISSN:
0167-2991
URN:
uuid:491735fb-723d-4f2f-9479-10dd8e6bc71b
Source identifiers:
180297
Local pid:
pubs:180297
Language:
English

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