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Dibenzotetraaza[14]annulenes: versatile ligands for transition and main group metal chemistry

Abstract:

This article presents an overview of the chemistry of metal complexes of dibenzotetraaza[14]annulene ligands and highlights most of the recent developments. The title tetraazamacrocycles are related to the porphyrins but have a smaller N4 coordination cavity 'hole size' and typically possess a non-planar, saddle-shaped conformation. The similarity of the dibenzotetraaza[14]annulenes to the porphyrins means that these synthetic macrocycles are of bioinorganic relevance, while their distinctive...

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Publication status:
Published

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Publisher copy:
10.1039/a827105z

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CHEMICAL SOCIETY REVIEWS
Volume:
27
Issue:
2
Pages:
105-115
Publication date:
1998-03-01
DOI:
EISSN:
1460-4744
ISSN:
0306-0012
Source identifiers:
51152
Language:
English
Pubs id:
pubs:51152
UUID:
uuid:48ac3af3-3064-43cf-b5af-4744cbb32d73
Local pid:
pubs:51152
Deposit date:
2012-12-19

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