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Thesis

Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions

Abstract:

This thesis documents the development of rhodium-catalyzed traceless chelation-controlled hydroacylation reactions for the synthesis of a variety of ketone products.

Chapter 1 provides an overview of rhodium-catalyzed hydroacylation chemistry, focusing on the origin of chelation-controlled strategies and the benefits thereof.

Chapter 2 describes a sequential reaction involving alkene hydroacylation, sulfide elimination and boronic acid conjug...

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Role:
Supervisor
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

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