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REDOX-RESPONSIVE CROWN ETHERS CONTAINING A CONJUGATED LINK BETWEEN THE FERROCENE MOIETY AND A BENZO CROWN ETHER

Abstract:

The syntheses of new redox-active crown ethers 8a, 8b, 9a, and 9b containing cis- and trans-conjugated olefinic linkages between the ferrocene redox center and respectively benzo-15-crown-5 and N-phenylaza-15-crown-5 are described. The sodium cation forms 1:1 stoichiometric complexes with the trans ferrocenyl ionophores 8b and 9b, whereas potassium produces 1:2 intermolecular sandwich complexes with the same ligands, which were also observed by fast atom bombardment mass spectrometry. Electro...

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Publication status:
Published

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Publisher copy:
10.1021/ic00328a006

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Journal:
INORGANIC CHEMISTRY
Volume:
29
Issue:
3
Pages:
378-381
Publication date:
1990-02-07
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:46c05076-2d8e-44fc-a2d2-2cf2dda4e4a0
Source identifiers:
46087
Local pid:
pubs:46087
Language:
English

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