Journal article
Sulfonamide, Phenolate, and Directing Ligand-Free Indium Initiators for the Ring-Opening Polymerization of rac-Lactide
- Abstract:
-
Reaction of In(CH2SiMe3)3 with H 2N2TsNpy or H2N 2TsNOMe gave the five-coordinate indium alkyls In(N2TsNpy)(CH2SiMe3) (14) and In(N2TsNOMe)(CH2SiMe 3) (15). The corresponding reaction with H2N 2TsNPh gave four-coordinate In(N 2TsNPh)(CH2SiMe3) (16). Reaction of H2N2TsNpy with In{N(SiMe3)2}3 gave the amide In(N 2TsNpy){N(SiMe3)2} (19). Reaction of Na2N2TsNpy with InCl3 in THF followed by LiOiPr gave the "ate" product In(N2TsNpy)(OiPr)Cl{Li(THF)} (21). The chloride complex In(N2TsNpy)Cl(py) (22...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- ORGANOMETALLICS
- Volume:
- 30
- Issue:
- 5
- Pages:
- 1202-1214
- Publication date:
- 2011-03-14
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- Source identifiers:
-
127249
Item Description
- Language:
- English
- Pubs id:
-
pubs:127249
- UUID:
-
uuid:45fbd060-e880-4a24-9b52-ddfd115b1fe8
- Local pid:
- pubs:127249
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2011
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