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Metal-directed self-assembly of terphenyl based dithiocarbamate ligands

Abstract:

The synthesis of dithiocarbamate ligands based on an m-terphenyl scaffold is reported. These ligands self-assemble with zinc(II), nickel(II) and copper(II) ions to afford neutral, dinuclear metallomacrocycles in varied yields. The assemblies have been characterised by a range of techniques, including 1H NMR,13C NMR and UV-vis spectroscopy, elemental analysis, mass spectrometry and cyclic voltammetry. Intramolecular coordination of bipyridyl guests has been investigated with the zinc(II) conta...

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Publication status:
Published

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Publisher copy:
10.1039/b106405c

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
22
Pages:
3367-3372
Publication date:
2001-01-01
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
URN:
uuid:4573a4f7-ecfe-498f-8a4f-8544edebabbe
Source identifiers:
38060
Local pid:
pubs:38060
Language:
English

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