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ELECTRON-PARAMAGNETIC RESONANCE STUDY OF THE REACTION OF GROUND-STATE AL ATOMS WITH NH3 IN A ROTATING CRYOSTAT

Abstract:

An electron paramagnetic resonance spectroscopic study of the reaction of ground-state Al atoms with NH3 in adamantane at 77 K on a rotating cryostat has demonstrated the formation of three mononuclear Al-NH3 complexes, Al(NH3)4 (A), HAlNH2 (B), and Al(NH3)2 (C). These species have the following magnetic parameters: aAl = 786.3 ± 0.22 MHz, aN = 23 ± 0.08 MHz, and g = 1.9997 ± 0.0001 for Al(NH3)4, aAl = 922.5 ± 0.41 MHz, aH = 228.7 ± 2.00 MHz, aN = 27 ± 2.0 MHz, aH(1) = 27 ± 2.0 MHz, and g = 2...

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Publication status:
Published

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Publisher copy:
10.1021/ja00028a012

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Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume:
114
Issue:
2
Pages:
474-477
Publication date:
1992-01-15
DOI:
ISSN:
0002-7863
URN:
uuid:445fb2b2-b249-47b2-93ac-29a4609eb687
Source identifiers:
43720
Local pid:
pubs:43720
Language:
English

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