- Abstract:
-
An electron paramagnetic resonance spectroscopic study of the reaction of ground-state Al atoms with NH3 in adamantane at 77 K on a rotating cryostat has demonstrated the formation of three mononuclear Al-NH3 complexes, Al(NH3)4 (A), HAlNH2 (B), and Al(NH3)2 (C). These species have the following magnetic parameters: aAl = 786.3 ± 0.22 MHz, aN = 23 ± 0.08 MHz, and g = 1.9997 ± 0.0001 for Al(NH3)4, aAl = 922.5 ± 0.41 MHz, aH = 228.7 ± 2.00 MHz, aN = 27 ± 2.0 MHz, aH(1) = 27 ± 2.0 MHz, and g = 2...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ja00028a012
-
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- Journal:
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume:
- 114
- Issue:
- 2
- Pages:
- 474-477
- Publication date:
- 1992-01-15
- DOI:
- ISSN:
-
0002-7863
- URN:
-
uuid:445fb2b2-b249-47b2-93ac-29a4609eb687
- Source identifiers:
-
43720
- Local pid:
- pubs:43720
- Language:
- English
- Copyright date:
- 1992
Journal article
ELECTRON-PARAMAGNETIC RESONANCE STUDY OF THE REACTION OF GROUND-STATE AL ATOMS WITH NH3 IN A ROTATING CRYOSTAT
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