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Anion templated assembly of an indolocarbazole containing pseudorotaxane on beads and silica nanoparticles

Abstract:
The surface covalent attachment of fluorescent axles of indolocarbazole enables anion templation to be exploited in the formation of pseudorotaxane assemblies via the threading of neutral isophthalamide macrocycles. In utilising the surface of polystyrene beads this threading process can be followed by both magnetic resonance methods and changes in the axle fluorescent emission spectrum. The analogous surface assembly and anion templated threading can be achieved, with fluoride and sulfate, on silica nanoparticles where anion recognition and macrocycle threading are associated with equivalent and specific optical change. © 2009 The Royal Society of Chemistry.
Publication status:
Published

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Publisher copy:
10.1039/b818854h

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Publisher:
Royal Society of Chemistry
Journal:
NEW JOURNAL OF CHEMISTRY More from this journal
Volume:
33
Issue:
4
Pages:
760-768
Publication date:
2009-01-01
DOI:
EISSN:
1369-9261
ISSN:
1144-0546


Language:
English
Pubs id:
pubs:41154
UUID:
uuid:443778bb-35e6-4565-98f2-0fea6009ea0a
Local pid:
pubs:41154
Source identifiers:
41154
Deposit date:
2012-12-19

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