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A new three-dimensional vanadium selenite, (VO)(2)(SeO3)(3), with isolated and edge-shared VO6 octahedra

Abstract:

Single crystals of (VO)2(SeO3)3 have been prepared from SeO2 and V2O5. The crystal structure has been determined by single-crystal X-ray diffraction. Crystal data: (VO)2(SeO3)3, Mr = 514.75; monoclinic, space group P21a (No. 14); cell parameters a = 9.151(1) Å, b = 6.353(1) Å, c = 14.992(1)Å, β = 93.538(5)°, and Z = 4. The structure consists of VO6 octahedra and SeO3 groups. The vanadium octahedra either are edge-sharing and form [V2O6.66]3.33- groups or are corner-linked through an [SeO3/2]+...

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Publication status:
Published

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Publisher copy:
10.1021/ic9708881

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
INORGANIC CHEMISTRY
Volume:
36
Issue:
27
Pages:
6409-6412
Publication date:
1997-12-31
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
51157
Language:
English
Pubs id:
pubs:51157
UUID:
uuid:43c874bf-fd1a-4a86-9a0b-5f3d1421cf6f
Local pid:
pubs:51157
Deposit date:
2012-12-19

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