- Abstract:
-
The basis for mass transport of the electroactive species in different diffusion fields is examined, pointing out important insights in relation to the value of the surface concentrations for the case of fast electrode processes. Moreover, a general analytical solution for the transient current is given for several geometries, when an arbitrary sequence of potentials pulses is applied to macroelectrodes (planar), spheres, cylinders, discs and bands. The results are particularized for Square W...
Expand abstract - Publication status:
- Published
- Journal:
- RUSSIAN JOURNAL OF ELECTROCHEMISTRY
- Volume:
- 48
- Issue:
- 6
- Pages:
- 600-609
- Publication date:
- 2012-06-05
- DOI:
- EISSN:
-
1608-3342
- ISSN:
-
1023-1935
- URN:
-
uuid:43923387-a2b7-4a5b-9c40-020b5bf660ac
- Source identifiers:
-
342045
- Local pid:
- pubs:342045
- Language:
- English
- Keywords:
- Copyright date:
- 2012
Journal article
Mass transport at electrodes of arbitrary geometry. Reversible charge transfer reactions in square wave voltammetry
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