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A new method for the study of processes at the liquid-liquid interface using an array of microdroplets on a au electrode.

Abstract:

We report the fabrication of partially blocked gold electrodes, with regularly and hexagonally spaced inert hydrophobic blocks on their surface. The hydrophobic blocks, with diameters of 5 mum, are used to support liquid 5-nonyl-salicylaldoxime (Acorga-P50) droplets on the surface. By voltametrically monitoring the transport-controlled reduction rate of Cu(II) (in pH 5 solution) at the unblocked part of the gold surface it is possible to deduce, via simulation, the parameters controlling the ...

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Publication status:
Published

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Publisher copy:
10.1002/cphc.200600394

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Journal:
Chemphyschem : a European journal of chemical physics and physical chemistry
Volume:
7
Issue:
12
Pages:
2585-2592
Publication date:
2006-12-05
DOI:
EISSN:
1439-7641
ISSN:
1439-4235
URN:
uuid:42f6c5ec-fab8-464e-9665-640751a55d0b
Source identifiers:
33662
Local pid:
pubs:33662

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