Journal article
Weak intermolecular CH···N hydrogen bonding: determination of 13CH–15N hydrogen-bond mediated J couplings by solid-state NMR spectroscopy and first-principles calculations
- Abstract:
-
Weak hydrogen bonds are increasingly hypothesized to play key roles in a wide range of chemistry from catalysis to gelation to polymer structure. Here, 15N/13C spin-echo magic-angle spinning (MAS) solid-state nuclear magnetic resonance (NMR) experiments are applied to “view” intermolecular CH···N hydrogen bonding in two selectively labeled organic compounds, 4-[15N] cyano-4′-[13C2] ethynylbiphenyl (1) and [15N3,13C6]-2,4,6-triethynyl-1,3,5-triazine (2). The synthesis of 2-15N3,13C6 is reporte...
Expand abstract
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Preview, Accepted manuscript, pdf, 687.4KB, Terms of use)
-
- Publisher copy:
- 10.1021/acs.jpca.9b10726
Authors
Funding
Bibliographic Details
- Publisher:
- American Chemical Society
- Journal:
- Journal of Physical Chemistry A More from this journal
- Volume:
- 124
- Issue:
- 3
- Pages:
- 560–572
- Publication date:
- 2019-12-27
- Acceptance date:
- 2019-12-27
- DOI:
- EISSN:
-
1520-5215
- ISSN:
-
1089-5639
Item Description
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:1080740
- UUID:
-
uuid:42a553aa-f0d1-41b7-bdf9-be2d29adefef
- Local pid:
-
pubs:1080740
- Source identifiers:
-
1080740
- Deposit date:
-
2020-01-02
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2019
- Rights statement:
- © 2019 American Chemical Society
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from the American Chemical Society at: https://doi.org/10.1021/acs.jpca.9b10726
Metrics
If you are the owner of this record, you can report an update to it here: Report update to this record