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A catenane assembled through a single charge-assisted halogen bond.

Abstract:
Getting connected: The formation of pseudorotaxane assemblies between a designed macrocyclic halogen bonding (XB) acceptor (red in scheme) and a series of XB donor threading components was templated by a single halogen bond. The strength of the XB assembly between the pyridine macrocycle and iodopyridinium thread was utilized in the ring-closing metathesis clipping synthesis of a [2]catenane. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201300464

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Caballero, A More by this author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
52
Issue:
16
Pages:
4356-4360
Publication date:
2013-04-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:426584a1-ae5c-480f-a361-31976f220526
Source identifiers:
387966
Local pid:
pubs:387966

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