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Hydration of sugars in the gas phase: regioselectivity and conformational choice in N-acetyl glucosamine and glucose.

Abstract:

The influence of an acetamido group in directing the preferred choice of hydration sites in glucosamine and a consequent extension of the working rules governing regioselective hydration and conformational choice, have been revealed through comparisons between the conformations and structures of "free" and multiply hydrated phenyl N-acetyl-beta-D-glucosamine (betapGlcNAc) and phenyl beta-D-glucopyranoside (betapGlc), isolated in the gas phase at low temperatures. The structures have been assi...

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Publication status:
Published

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Publisher copy:
10.1002/chem.200901830

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Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
15
Issue:
48
Pages:
13427-13434
Publication date:
2009-12-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:418b1680-851e-47b0-b195-31997c625193
Source identifiers:
34966
Local pid:
pubs:34966

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