- Abstract:
-
The influence of an acetamido group in directing the preferred choice of hydration sites in glucosamine and a consequent extension of the working rules governing regioselective hydration and conformational choice, have been revealed through comparisons between the conformations and structures of "free" and multiply hydrated phenyl N-acetyl-beta-D-glucosamine (betapGlcNAc) and phenyl beta-D-glucopyranoside (betapGlc), isolated in the gas phase at low temperatures. The structures have been assi...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/chem.200901830
-
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- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Volume:
- 15
- Issue:
- 48
- Pages:
- 13427-13434
- Publication date:
- 2009-12-05
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- URN:
-
uuid:418b1680-851e-47b0-b195-31997c625193
- Source identifiers:
-
34966
- Local pid:
- pubs:34966
- Language:
- English
- Keywords:
- Copyright date:
- 2009
Journal article
Hydration of sugars in the gas phase: regioselectivity and conformational choice in N-acetyl glucosamine and glucose.
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