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Topotactic synthesis of layered double hydroxide nanorods

Abstract:
Layered double hydroxide [LiAl 2(OH) 6]X (LiAl-X; X = Cl, Br) 1D nanorods have been prepared in a topotactic reaction involving the intercalation of LiX (X = Cl, Br) into a rod-like form of gibbsite. The nanorod LDH products adopt a hexagonal prismatic morphology with the brucite-like layers stacking along the long rod axis. These materials are able to undergo anion-exchange reactions to give organic intercalated rod-like LDH materials. © 2012 The Royal Society of Chemistry.
Publication status:
Published

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Publisher copy:
10.1039/c2jm34670b

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
22
Issue:
43
Pages:
23064-23070
Publication date:
2012-11-21
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:415c25b2-2539-450a-ae82-9d782d01e9ec
Source identifiers:
366408
Local pid:
pubs:366408
Language:
English

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