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Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands

Abstract:

The synthesis and reactivity of titanium diphenyl hydrazido(2-) complexes supported by the diamido-ether ligands O(2-C6H4NSiMe 3)2 (N2ArO) and O(CH 2CH2NSiMe3)2 (N2O) are described. Reaction of Li2N2ArO or Li 2N2O with Ti(NNPh2)Cl2(py) 3 afforded Ti(N2ArO)(NNPh2)(py) 2 (14) or Ti(N2O)(NNPh2)(py)2 (15) with κ3-mer-bound diamido-ether ligands. Reaction with tBu-bipy (4,4′-di-tert-butyl-2,2′-bipyridyl) or bipy (2,2′-bipyridyl) gave a switch to κ3-fac-coordination. Reaction of 15 with Ar′NCO (Ar′...

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Publication status:
Published

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Publisher copy:
10.1021/om400311w

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS
Volume:
32
Issue:
10
Pages:
3091-3107
Publication date:
2013-05-27
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:403963
UUID:
uuid:41368472-395b-447f-a49e-2981c85801d5
Local pid:
pubs:403963
Source identifiers:
403963
Deposit date:
2013-11-17

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