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[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.

Abstract:
The bimetallic complex [V(Cp)]2Pn, containing a V-V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.
Publication status:
Published

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Publisher copy:
10.1039/b306688f

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
9
Issue:
17
Pages:
2208-2209
Publication date:
2003-09-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
51199
Language:
English
Pubs id:
pubs:51199
UUID:
uuid:41133f39-6b7d-44d8-a0af-a0b8db536451
Local pid:
pubs:51199
Deposit date:
2012-12-19

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