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Thesis

Topochemical reactions of ruthenium and rhodium containing oxide phases

Abstract:

This work is focussed on the topochemical reactions of Ru-containing and Rh-containing n = 1 Ruddlesden-Popper phases by using CaH2 as a reducing agent, to form oxide-hydride phases, or finely divided Zr powder as an oxygen getter, to form anion-deficient reduced oxide phases. The chemical doping of LaSr3NiRuO8 and LaSr3NiRuO4H4 is also been investigated.

Building on the work of the first Ru(II)-containing cation-orde...

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Role:
Supervisor
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Grant:
RPG-2014-366
Funding agency for:
Project
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

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