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Intracluster stereochemistry in van der Waals complexes: steric effects in ultraviolet photodissociation of state-selected Ar-HOD/H2O.

Abstract:

High-resolution IR-UV multiple resonance methods are employed to elucidate the photodissociation dynamics of quantum state-selected Ar-HOD and Ar-H(2)O van der Waals clusters. A single mode pulsed OPO operating in the region of the OH second overtone is used to prepare individual rovibrational states that are selectively photodissociated at specific excimer wavelengths. Subsequent fluorescence excitation of the resulting OH (OD) fragments yields dynamical information on the photofragmentation...

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Publication status:
Published

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Publisher copy:
10.1063/1.1697394

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Journal of chemical physics
Volume:
120
Issue:
18
Pages:
8443-8452
Publication date:
2004-05-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:59005
UUID:
uuid:4093282a-e76f-4c1e-aa71-65ffaff31696
Local pid:
pubs:59005
Source identifiers:
59005
Deposit date:
2012-12-19

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