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Metal-to-ligand charge-transfer sensitisation of near-infrared emitting lanthanides in trimetallic arrays M2Ln (M=Ru, Re or Os; Ln=Nd, Er or Yb).

Abstract:

The new pro-ligand 4-methyl-4'-(carbonylamino(2-(tert-butoxycarbonylamino)ethyl))-2,2'-bipyridyl (L1) has been prepared and used to synthesise the complex fac-Re(I)Cl(CO)3(L1) 1 and the complex salts [M(II)(bipy)2(L1)](PF6)2 (M=RuII 8 or OsII 15). Deprotection with trifluoroacetic acid affords the amine-functionalised derivatives fac-Re(I)Cl(CO)3(L2) 2, [M(II)(bipy)2(L2)](PF6)2 (M=RuII 9 or OsII 16) which react with the dianhydride of diethylenetriamine pentaacetic acid (DTPA) to give the bin...

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Publication status:
Published

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Publisher copy:
10.1039/b500849b

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
8
Pages:
1482-1490
Publication date:
2005-04-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Source identifiers:
33057
Language:
English
Pubs id:
pubs:33057
UUID:
uuid:4062c195-35d9-4db3-a3fe-3d8fbfd0259d
Local pid:
pubs:33057
Deposit date:
2012-12-19

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