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SPECTROSCOPY AND DYNAMICS OF RARE GAS-SPHERICAL TOP COMPLEXES - THE INFRARED-SPECTRUM OF THE NU(3) BAND OF ARGON-SILANE

Abstract:

The infrared spectrum of Ar-SiH4, a rare gas-spherical top van der Waals complex, has been recorded in the vicinity of the silane ν3 triply degenerate stretching vibration ∼2189 cm -1. A complex, dense spectrum is observed, and this is due to the observation of 12 bands with origins corresponding to transitions between different internal rotor states of the silane molecule within the complex. From the analysis of the rotational structure within each band, the average argon-silane separation i...

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Publication status:
Published

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Publisher copy:
10.1063/1.466905

Authors


RANDALL, R More by this author
IBBOTSON, J More by this author
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
100
Issue:
10
Pages:
7051-7060
Publication date:
1994-05-15
DOI:
ISSN:
0021-9606
URN:
uuid:3ff1e81b-a1e5-41f6-b511-432c7d7e6c86
Source identifiers:
44528
Local pid:
pubs:44528
Language:
English

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