- Abstract:
-
The infrared spectrum of Ar-SiH4, a rare gas-spherical top van der Waals complex, has been recorded in the vicinity of the silane ν3 triply degenerate stretching vibration ∼2189 cm -1. A complex, dense spectrum is observed, and this is due to the observation of 12 bands with origins corresponding to transitions between different internal rotor states of the silane molecule within the complex. From the analysis of the rotational structure within each band, the average argon-silane separation i...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1063/1.466905
-
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- Journal:
- JOURNAL OF CHEMICAL PHYSICS
- Volume:
- 100
- Issue:
- 10
- Pages:
- 7051-7060
- Publication date:
- 1994-05-15
- DOI:
- ISSN:
-
0021-9606
- URN:
-
uuid:3ff1e81b-a1e5-41f6-b511-432c7d7e6c86
- Source identifiers:
-
44528
- Local pid:
- pubs:44528
- Language:
- English
- Copyright date:
- 1994
Journal article
SPECTROSCOPY AND DYNAMICS OF RARE GAS-SPHERICAL TOP COMPLEXES - THE INFRARED-SPECTRUM OF THE NU(3) BAND OF ARGON-SILANE
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