Journal article
Catalytic Hypervalent Iodine Promoters Lead to Styrene Dimerization and the Formation of Tri- and Tetrasubstituted Cyclobutanes
- Abstract:
- We report that the use of catalytic quantities of hypervalent iodine reagents (PIDA or Dess Martin Periodinane) allows the rapid and stereoselective formation of cyclobutanes under very mild conditions. The presence of a fluorinated solvent is essential for the success of these reactions which are able to form unsymmetrical tri- and tetrasubstituted cyclobutanes via a heterodimerisation process involving two different alkenes.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
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(Accepted manuscript, pdf, 1.0MB)
-
(Accepted manuscript, pdf, 7.8MB)
-
- Publisher copy:
- 10.1002/ange.201511683
Authors
Funding
European Commission
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European Union
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Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 128
- Issue:
- 15
- Pages:
- 4826–4830
- Publication date:
- 2016-03-04
- Acceptance date:
- 2016-01-26
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
Item Description
- Pubs id:
-
pubs:600060
- UUID:
-
uuid:3f49caea-2d02-4ba2-b831-fcbb0e62c5b2
- Local pid:
- pubs:600060
- Source identifiers:
-
600060
- Deposit date:
- 2016-02-10
Terms of use
- Copyright holder:
- Wiley-VCH Verlag
- Copyright date:
- 2016
- Notes:
- © 2016 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim. Published on behalf of Gesellschaft Deutscher Chemiker (GDCh). This is the accepted manuscript version of the article. The final version is available online from Wiley at [10.1002/ange.201511683].
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