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Journal article

Synthesis and molecular and electronic structure of an unusual paramagnetic borohydride complex Mo(NAr)2(PMe3)2(eta2-BH4).

Abstract:

Reaction of Mo(NAr)2Cl2(DME) (Ar=2,6-C6H3iPr2, DME=1,2-dimethoxyethane) with NaBH4 and PMe3 in THF formed the paramagnetic Mo(V) d1 borohydride complex Mo(NAr)2(PMe3)2(eta2-BH4) (1). Compound 1, which was characterized by EPR spectroscopy and X-ray diffraction analysis, provides a rare example both of a paramagnetic bis(imido) group 6 compound and a structurally characterized molybdenum borohydride complex. Density functional theory calculations were used to determine the electronic structure...

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Publication status:
Published

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Publisher copy:
10.1021/ic701826v

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Inorganic chemistry
Volume:
47
Issue:
3
Pages:
999-1006
Publication date:
2008-02-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
34092
Language:
English
Pubs id:
pubs:34092
UUID:
uuid:3efedcf9-91a5-4036-b399-c7644f712b23
Local pid:
pubs:34092
Deposit date:
2012-12-19

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