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Synthesis and molecular and electronic structure of an unusual paramagnetic borohydride complex Mo(NAr)2(PMe3)2(eta2-BH4).

Abstract:

Reaction of Mo(NAr)2Cl2(DME) (Ar=2,6-C6H3iPr2, DME=1,2-dimethoxyethane) with NaBH4 and PMe3 in THF formed the paramagnetic Mo(V) d1 borohydride complex Mo(NAr)2(PMe3)2(eta2-BH4) (1). Compound 1, which was characterized by EPR spectroscopy and X-ray diffraction analysis, provides a rare example both of a paramagnetic bis(imido) group 6 compound and a structurally characterized molybdenum borohydride complex. Density functional theory calculations were used to determine the electronic structure...

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Publication status:
Published

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Publisher copy:
10.1021/ic701826v

Authors


Khalimon, AY More by this author
Holland, JP More by this author
Kowalczyk, RM More by this author
McInnes, EJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Journal:
Inorganic chemistry
Volume:
47
Issue:
3
Pages:
999-1006
Publication date:
2008-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:3efedcf9-91a5-4036-b399-c7644f712b23
Source identifiers:
34092
Local pid:
pubs:34092
Language:
English

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