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FLP-mediated activations and reductions of CO2 and CO

Abstract:

This chapter reviews the published work to date on the interaction of CO2 and CO with frustrated Lewis pairs (FLPs). The ability of FLP-derived systems reversibly to bind and release CO2 is a dramatic and exciting development, offering new routes to sequester this environmentally important molecule. Furthermore, in combination with FLPs' documented ability to cleave H2 heterolytically, new CO2 hydrogenation chemistry has been uncovered. Novel tandem catalytic processes involving FLPs are begi...

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Publisher copy:
10.1007/128-2012-377

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Journal:
Topics in Current Chemistry
Volume:
334
Pages:
191-218
Publication date:
2013-01-01
DOI:
ISSN:
0340-1022
URN:
uuid:3e521a94-718d-41f6-b81f-c6f7830c1cd2
Source identifiers:
449045
Local pid:
pubs:449045

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