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Incorporation of phosphorus oxyacids into layered double hydroxides

Abstract:

Four phosphonate anions (methyl-, ethyl-, phenyl- and benzylphosphonate) were successfully incorporated into [Cu2Cr(OH)6]Cl·yH2O. It was found that two phases exist for the phenylphosphonate intercalate; one in which the anions are arranged perpendicular to the layers, and one with a tilted orientation. Systematic variation of the reaction conditions allowed the former to be isolated with phase purity, but not the latter. The solid-state 31P NMR data suggest that proton transfer may occur bet...

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Publication status:
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
SOLID STATE SCIENCES
Volume:
11
Issue:
7
Pages:
1229-1238
Publication date:
2009-07-01
DOI:
ISSN:
1293-2558
Source identifiers:
51252
Language:
English
Keywords:
Pubs id:
pubs:51252
UUID:
uuid:3dccdea0-7055-4e0f-a032-4576df35a3ea
Local pid:
pubs:51252
Deposit date:
2012-12-19

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