Cs-133 NMR and ESR Studies of Cesium-Loaded LiX and LiA Zeolites

Journal article

The species generated when cesium metal was loaded into zeolites LiA, LiX, and LiLSX by vapor deposition were systematically investigated by 133Cs NMR and ESR as a function of loading level. The primary 133Cs NMR signal in Cs-loaded LiA at low loading was assigned to Cs+ in the eight-ring SII sites and showed axial anisotropy of the chemical shift. The primary 133Cs NMR signal in Cs-loaded LiX and LiLSX was isotropic and was assigned to Cs+ dynamically exchanging among the SIII sites. This dy...

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Authors: Reinhold, C; Anderson, P; Edwards, P; Terskikh, V; Ratcliffe, C

• Publication status: Published
• Journal: JOURNAL OF PHYSICAL CHEMISTRY C
• Volume: 112
• Issue: 46
• Pages: 17796-17803
• Publication date: 2008-11-20
• DOI: 10.1021/jp803987h
• EISSN: 1932-7455
• ISSN: 1932-7447
• Language: English