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Resorcarene-Based Nanoarchitectures: Metal-Directed Assembly of a Molecular Loop and Tetrahedron.

Abstract:
Large cavities and portals are present in the nanoscale molecular architectures formed from dithiocarbamate-functionalized resorcarene ligands and zinc(II) or copper(III) ions. With Zn(II) a molecular loop based on a triangle of resorcarene cups is prepared-the cavity is circular (shown on the left). A molecular cage based on a distorted tetrahedron of four resorcarene ligands assembled by eight Cu(III) ions contains triangular-shaped portals suitable for guest passage (shown on the right).

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Angewandte Chemie (International ed. in English)
Volume:
39
Issue:
1
Pages:
135-140
Publication date:
2000-01-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:3c30b47d-8f18-4758-b78d-3cea32de3949
Source identifiers:
31612
Local pid:
pubs:31612
Language:
English

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