- Abstract:
- Large cavities and portals are present in the nanoscale molecular architectures formed from dithiocarbamate-functionalized resorcarene ligands and zinc(II) or copper(III) ions. With Zn(II) a molecular loop based on a triangle of resorcarene cups is prepared-the cavity is circular (shown on the left). A molecular cage based on a distorted tetrahedron of four resorcarene ligands assembled by eight Cu(III) ions contains triangular-shaped portals suitable for guest passage (shown on the right).
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- Journal:
- Angewandte Chemie (International ed. in English)
- Volume:
- 39
- Issue:
- 1
- Pages:
- 135-140
- Publication date:
- 2000-01-05
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- URN:
-
uuid:3c30b47d-8f18-4758-b78d-3cea32de3949
- Source identifiers:
-
31612
- Local pid:
- pubs:31612
- Language:
- English
- Copyright date:
- 2000
Journal article
Resorcarene-Based Nanoarchitectures: Metal-Directed Assembly of a Molecular Loop and Tetrahedron.
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