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Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates

Abstract:
Alkylation studies on the enolate of N-methyl morpholinone 7 clearly reveal that the observed cis-selectivity is consistent with a chiral relay system operating to invert the stereochemical information of the auxiliary's C5 stereogenic centre.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON-ASYMMETRY
Volume:
9
Issue:
9
Pages:
1483-1487
Publication date:
1998-05-08
DOI:
ISSN:
0957-4166
Source identifiers:
110634
Language:
English
Pubs id:
pubs:110634
UUID:
uuid:3ba1f17d-de26-4c70-9140-f8819d434a6e
Local pid:
pubs:110634
Deposit date:
2012-12-19

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