Journal article icon

Journal article

Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium(ii)

Abstract:

A 500 MHz NMR study of the reaction between 1-tetralone oxime and PdCl42− in CD3OD shows resonances attributable to a potential agostic intermediate prior to the formation of the insoluble cyclopalladated product which itself was characterised by X-ray crystallography. Calculated structural, spectroscopic, QTAIM, NBO and NCI analysis results obtained from density functional theory (DFT) calculations give a full d...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

Actions


Access Document


Files:
Publisher copy:
10.1039/c7dt03525j

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
Expand authors...
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
46
Pages:
16126-16138
Publication date:
2017-11-02
Acceptance date:
2017-11-02
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Pubs id:
pubs:746097
URN:
uri:3b9cec36-8913-4199-837c-d07bd7baa2a3
UUID:
uuid:3b9cec36-8913-4199-837c-d07bd7baa2a3
Local pid:
pubs:746097
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP