- Abstract:
-
A 500 MHz NMR study of the reaction between 1-tetralone oxime and PdCl42− in CD3OD shows resonances attributable to a potential agostic intermediate prior to the formation of the insoluble cyclopalladated product which itself was characterised by X-ray crystallography. Calculated structural, spectroscopic, QTAIM, NBO and NCI analysis results obtained from density functional theory (DFT) calculations give a full d...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 1.9MB)
-
(pdf, 1.4MB)
-
- Publisher copy:
- 10.1039/c7dt03525j
-
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- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton Transactions Journal website
- Volume:
- 46
- Pages:
- 16126-16138
- Publication date:
- 2017-11-02
- Acceptance date:
- 2017-11-02
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- Pubs id:
-
pubs:746097
- URN:
-
uri:3b9cec36-8913-4199-837c-d07bd7baa2a3
- UUID:
-
uuid:3b9cec36-8913-4199-837c-d07bd7baa2a3
- Local pid:
- pubs:746097
- Language:
- English
- Copyright holder:
- Sajjad et al.
- Copyright date:
- 2017
- Notes:
-
Copyright © the Authors. This is the accepted manuscript version of the article. The final version is available online from the Royal Society of Chemistry at: https://doi.org/10.1039/c7dt03525j
Journal article
Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium(ii)
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