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INTRAMOLECULAR REARRANGEMENT IN THE INFRARED MULTIPLE-PHOTON DISSOCIATION OF DICHLORODIFLUOROETHYLENE

Abstract:

The infrared multiple-photon dissociation (IRMPD) of 1,1-dichloro-2,2-difluoroethylene, CF2=CCl2, has been investigated. Under essentially collisionless photolysis conditions, four electronic ground-state radical fragments, CF2(X̃1A1), CCl2(X̃1A1), CFCl(X̃1A′), and CCl(X2II), were detected directly by laser-induced fluorescence (LIF). Production of atomic Cl was also inferred by an indirect infrared chemiluminescence technique. The ratio of products CF2:CFCl:Cl was established within limiting...

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Publication status:
Published

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Publisher copy:
10.1021/j100318a029

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
MCKENDRICK, K More by this author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY
Volume:
92
Issue:
7
Pages:
1839-1846
Publication date:
1988-04-07
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
URN:
uuid:3b3aced5-b29a-4da4-aa72-e76535a24e85
Source identifiers:
42914
Local pid:
pubs:42914
Language:
English

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