- Abstract:
-
The infrared multiple-photon dissociation (IRMPD) of 1,1-dichloro-2,2-difluoroethylene, CF2=CCl2, has been investigated. Under essentially collisionless photolysis conditions, four electronic ground-state radical fragments, CF2(X̃1A1), CCl2(X̃1A1), CFCl(X̃1A′), and CCl(X2II), were detected directly by laser-induced fluorescence (LIF). Production of atomic Cl was also inferred by an indirect infrared chemiluminescence technique. The ratio of products CF2:CFCl:Cl was established within limiting...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/j100318a029
-
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- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY
- Volume:
- 92
- Issue:
- 7
- Pages:
- 1839-1846
- Publication date:
- 1988-04-07
- DOI:
- EISSN:
-
1541-5740
- ISSN:
-
0022-3654
- URN:
-
uuid:3b3aced5-b29a-4da4-aa72-e76535a24e85
- Source identifiers:
-
42914
- Local pid:
- pubs:42914
- Language:
- English
- Copyright date:
- 1988
Journal article
INTRAMOLECULAR REARRANGEMENT IN THE INFRARED MULTIPLE-PHOTON DISSOCIATION OF DICHLORODIFLUOROETHYLENE
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