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Journal article

Anion-templated assembly of [2]rotaxanes.

Abstract:

Anion templation is used to develop a general method for rotaxane synthesis. The anion-templated synthesis of three new [2]rotaxanes containing positively charged pyridinium axles and neutral isophthalamide macrocyclic components is described. The incorporation of electron withdrawing substituents, such as the nitro group, into the 5-position of an isophthalamide bis-vinyl acyclic precursor results in a significant improvement in [2]rotaxane assembly yields. Rotaxane anion binding strengths a...

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Publication status:
Published

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Publisher copy:
10.1039/b518178j

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Organic and biomolecular chemistry
Volume:
4
Issue:
8
Pages:
1529-1538
Publication date:
2006-04-01
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
Source identifiers:
33440
Language:
English
Pubs id:
pubs:33440
UUID:
uuid:3a96d9f0-3bad-4c36-a4c2-7875321df2c8
Local pid:
pubs:33440
Deposit date:
2012-12-19

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