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Can heterometallic 1-dimensional chains support current rectification?

Abstract:
To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios.
Publication status:
Published

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Publisher copy:
10.1039/c3cc45063e

Authors


Journal:
Chemical Communications
Volume:
49
Issue:
80
Pages:
9116-9118
Publication date:
2013-10-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
421071
Language:
English
Pubs id:
pubs:421071
UUID:
uuid:3a93b2c1-ac18-4da9-a7ed-9adf8479c75f
Local pid:
pubs:421071
Deposit date:
2013-11-16

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