- Abstract:
- We study mechanical flexibility and its link to optical properties in the dense metal–organic framework silver(I) dicyanamide, Ag[N(CN)2]. We show that the system exhibits polymorph-independent anomalous thermal expansion behaviour and find a linear variation in the relative intensity of emission bands with temperature, indicative of thermochromism in the Ag-centered luminescence.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted manuscript
- Files:
-
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(pdf, 2.9MB)
-
- Publisher copy:
- 10.1002/ejic.201600246
-
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- Funding agency for:
- Goodwin, AL
- Publisher:
- Wiley Publisher's website
- Journal:
- European Journal of Inorganic Chemistry Journal website
- Volume:
- 2016
- Issue:
- 27
- Pages:
- 4378–4381
- Publication date:
- 2016-06-05
- DOI:
- ISSN:
-
1434-1948
- URN:
-
uuid:3a31c51f-b9af-4cf5-b94a-ff1dc13d491a
- Source identifiers:
-
634506
- Local pid:
- pubs:634506
- Copyright holder:
- WILEY-VCH Verlag
- Copyright date:
- 2016
- Notes:
- © 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim
Journal article
Anomalous thermal expansion and luminescence thermochromism in silver(I) dicyanamide
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+ Engineering and Physical Sciences Research Council
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