Simulation of square wave voltammetry: Quasi-reversible electrode processes

Journal article

Simulations, based on the backward implicit method, for the square wave voltammetry (SWV) experiment are reported for the general case of quasi-reversible Butler-Volmer kinetics and a finite diffusion layer thickness. In the limiting cases of fast electrode kinetics, or semi-infinite diffusion, the results are in excellent agreement with independent calculations confirming the validity of the approach and its implementation. Under the previously unexplored conditions of finite diffusion, the ...

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Authors: Brookes, B; Compton, R

• Publication status: Published
• Journal: JOURNAL OF PHYSICAL CHEMISTRY B
• Volume: 103
• Issue: 42
• Pages: 9020-9028
• Publication date: 1999-10-21
• DOI: 10.1021/jp991508v
• EISSN: 1520-5207
• ISSN: 1089-5647
• Language: English