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2,3,4,6-Tetra-O-benzoyl-4-nitro-phenyl-1-thio-α-d-mannopyran-oside-dichloro-methane-diethyl ether mixed solvate (1/0.53/0.38).

Abstract:
The title compound, C(40)H(31)NO(11)S·0.53CH(2)Cl(2)·0.38C(4)H(10)O, was synthesized in two steps from mannose penta-acetate and single crystals were grown by slow evaporation. The structure was determined by single-crystal X-ray diffraction, confirming the α-configuration of the anomeric thioaryl substituent. The asymmetric unit contains two crystallographically distinct mol-ecules of the carbohydrate. The central pyran-ose rings of these are geometrically similar, but there are differences in the orientations of the benzoate substituents.
Publication status:
Published

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Publisher copy:
10.1107/s1600536807064951

Authors


Cowley, AR More by this author
Fairbanks, AJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Acta crystallographica. Section E, Structure reports online
Volume:
64
Issue:
Pt 1
Pages:
o236
Publication date:
2007
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:395f6a12-2a1a-4564-b794-ea2f8f1961f1
Source identifiers:
117159
Local pid:
pubs:117159
Language:
English

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