The reduction of oxygen in various room temperature ionic liquids in the temperature range 293-318 K: exploring the applicability of the Stokes-Einstein relationship in room temperature ionic liquids.

Journal article

The voltammetry for the reduction of oxygen at a microdisk electrode is reported in six commonly used RTILs: [C(4)mim][NTf(2)], [C(4)mpyrr][NTf(2)], [C(4)dmim][NTf(2)], [C(4)mim][BF(4)], [C(4)mim][PF(6)], and [N(6,2,2,2)][NTf(2)], where [C(4)mim](+) is 1-butyl-3-methylimidazolium, [NTf(2)](-) is bis(trifluoromethanesulfonyl)imide, [C(4)mpyrr](+) is N-butyl-N-methylpyrrolidinium, [C(4)dmim](+) is 1-butyl-2,3-methylimidazolium, [BF(4)](-) is tetrafluoroborate, [PF(6)](-) is hexafluorophosphate,...

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Authors: Huang, X; Rogers, E; Hardacre, C; Compton, R

• Publication status: Published
• Journal: journal of physical chemistry. B
• Volume: 113
• Issue: 26
• Pages: 8953-8959
• Publication date: 2009-07-01
• DOI: 10.1021/jp903148w
• EISSN: 1520-5207
• ISSN: 1520-6106
• Language: English