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The reduction of oxygen in various room temperature ionic liquids in the temperature range 293-318 K: exploring the applicability of the Stokes-Einstein relationship in room temperature ionic liquids.

Abstract:

The voltammetry for the reduction of oxygen at a microdisk electrode is reported in six commonly used RTILs: [C(4)mim][NTf(2)], [C(4)mpyrr][NTf(2)], [C(4)dmim][NTf(2)], [C(4)mim][BF(4)], [C(4)mim][PF(6)], and [N(6,2,2,2)][NTf(2)], where [C(4)mim](+) is 1-butyl-3-methylimidazolium, [NTf(2)](-) is bis(trifluoromethanesulfonyl)imide, [C(4)mpyrr](+) is N-butyl-N-methylpyrrolidinium, [C(4)dmim](+) is 1-butyl-2,3-methylimidazolium, [BF(4)](-) is tetrafluoroborate, [PF(6)](-) is hexafluorophosphate,...

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Publication status:
Published

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Publisher copy:
10.1021/jp903148w

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
journal of physical chemistry. B
Volume:
113
Issue:
26
Pages:
8953-8959
Publication date:
2009-07-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Source identifiers:
34742
Language:
English
UUID:
uuid:392ac8ab-6bc8-445d-a294-f5409c438ce7
Local pid:
pubs:34742
Deposit date:
2012-12-19

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