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Self-Assembled Conjugated Thiophene-Based Rotaxane Architectures: Structural, Computational, and Spectroscopic Insights into Molecular Aggregation

Abstract:: A comparative study of the self-assembly at a variety of surfaces of a dithiophene rotaxane 1⊂β-CD and its corresponding dumbbell, 1, by means of atomic force microscopy (AFM) imaging and scanning tunneling microscopy (STM) imaging on the micrometer and nanometer scale, respectively. The dumbbell is found to have a greater propensity to form ordered supramolecular assemblies, as a result of π-π interactions between dithiophenes belonging to adjacent molecules, which are hindered in the rotaxa...
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APA Style

Zalewski, L., Brovelli, S., Bonini, M., Mativetsky, J., Wykes, M., Orgiu, E., Breiner, T., Kastler, M., Doetz, F., Meinardi, F., Anderson, H., Beljonne, D., Cacialli, F., & Samori, P. (2011). Self-Assembled Conjugated Thiophene-Based Rotaxane Architectures: Structural, Computational, and Spectroscopic Insights into Molecular Aggregation. ADVANCED FUNCTIONAL MATERIALS, 21(5), 834–844.

MLA Style

Zalewski, L., et al. “Self-Assembled Conjugated Thiophene-Based Rotaxane Architectures: Structural, Computational, and Spectroscopic Insights into Molecular Aggregation.” ADVANCED FUNCTIONAL MATERIALS, vol. 21, no. 5, 2011, pp. 834–44.

Chicago Style

Zalewski, L, S Brovelli, M Bonini, J Mativetsky, M Wykes, E Orgiu, T Breiner, et al. 2011. “Self-Assembled Conjugated Thiophene-Based Rotaxane Architectures: Structural, Computational, and Spectroscopic Insights into Molecular Aggregation.” ADVANCED FUNCTIONAL MATERIALS 21 (5): 834–44.
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Publisher copy:: 10.1002/adfm.201001135

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+ Zalewski, L More by this author

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+ Brovelli, S More by this author

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+ Bonini, M More by this author

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+ Mativetsky, J More by this author

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+ Wykes, M More by this author

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Bibliographic Details

Journal:: ADVANCED FUNCTIONAL MATERIALS
Volume:: 21
Issue:: 5
Pages:: 834-844
Publication date:: 2011-03-08
DOI:: 10.1002/adfm.201001135
EISSN:: 1616-3028
ISSN:: 1616-301X

Item Description

Language:: English
Keywords:: rotaxanes

conjugated materials

self-assembly
Pubs id:: pubs:127328
UUID:: uuid:39177a83-82a3-47d2-aa46-9eb5dad2a52b
Local pid:: pubs:127328
Source identifiers:: 127328
Deposit date:: 2012-12-19

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Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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