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Conversion of propanal to pentan-3-one using lanthanide oxides

Abstract:

The heterogeneous reaction between propanal vapour and rare-earth-metal oxides gives as major products pentan-3-one and carbon dioxide. Residence time investigations indicate that pentan-3-one and carbon dioxide are primary products. Deactivation and high-resolution electron microscopy studies support the hypothesis that surface [O] participates in the reaction, and high oxygen mobilites in the oxide may allow defects to spread within the oxide. The carbon dioxide produced in the reaction poi...

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Publisher copy:
10.1039/FT9938901089

Authors


Journal:
Journal of the Chemical Society, Faraday Transactions
Volume:
89
Issue:
7
Pages:
1089-1094
Publication date:
1993-01-01
DOI:
ISSN:
0956-5000
Source identifiers:
180191
Language:
English
Pubs id:
pubs:180191
UUID:
uuid:38ae326e-56a1-474b-aac9-f306dbd24d65
Local pid:
pubs:180191
Deposit date:
2012-12-19

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