Journal article
Colorimetric metal-free detection of carbon monoxide: reversible CO uptake by a BNB frustrated Lewis pair
- Abstract:
-
We report two BNB-type frustrated Lewis pairs which feature an acceptor-donor-acceptor functionalized cavity, and which differ in the nature of the B-bound fluoroaryl group (C6F5 vs. C6H3(CF3)2-3,5, Arf). These receptor systems are capable of capturing gaseous CO, and in the case of the -BArf2 system this can be shown to occur in reversible fashion at/above room temperature. For both systems, the binding event is accompanied by migration of one of the aryl substituents to the electrophilic ca...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Funding
Leverhulme Trust
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Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 60
- Issue:
- 30
- Pages:
- 16416-16419
- Publication date:
- 2021-06-22
- Acceptance date:
- 2021-05-28
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Pmid:
-
34047424
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
1183988
- Local pid:
- pubs:1183988
- Deposit date:
- 2022-01-11
Terms of use
- Copyright holder:
- Zheng et al.
- Copyright date:
- 2021
- Rights statement:
- © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
- Licence:
- CC Attribution (CC BY)
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