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Xe+ formation following photolysis of Au-Xe: a velocity map imaging study.

Abstract:

The photodissociation dynamics of Au-Xe leading to Xe(+) formation via the Ξ(1∕2)-X(2)Σ(+) (v('), 0) band system (41 500-41 800 cm(-1)) have been investigated by velocity map imaging. Five product channels have been indentified, which can be assigned to photoinduced charge transfer followed by photodissociation in either the neutral or the [Au-Xe](+) species. For the neutral species, charge transfer occurs via a superexcited Rydberg state prior to dissociative ionization, while single-photon ...

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Publication status:
Published

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Publisher copy:
10.1063/1.3556944

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The Journal of chemical physics
Volume:
134
Issue:
9
Pages:
094311
Publication date:
2011-03-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:38938a96-bbac-460e-84f7-5ba8d6a388b5
Source identifiers:
124337
Local pid:
pubs:124337
Language:
English

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