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Zirconium and hafnium permethylpentalene compounds

Abstract:

A selection of new n8-permethylpentalene zirconium and hafnium complexes are reported. The first d-block metal bis(permethylpentalene) sandwich complexes, (Pn∗2M; Pn∗ = C8Me6; M = Zr, Hf) have been synthesized and structurally characterized. The bis-allyl species Pn∗M(C3H5)2 (M = Zr, Hf) have been synthesized; these complexes are fluxional in solution and react with CO2 to give the double-insertion product Pn∗M(2-O2CCH2CHCH2)2 (M = Zr, Hf). We also report monometallic, bimetallic, and polymer...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1021/acs.organomet.6b00301

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
35
Issue:
12
Pages:
2092-2100
Publication date:
2016-06-05
Acceptance date:
2016-05-31
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Pubs id:
pubs:634421
URN:
uri:3874fef7-5fc3-4a95-bdd4-b8166601cf0e
UUID:
uuid:3874fef7-5fc3-4a95-bdd4-b8166601cf0e
Local pid:
pubs:634421
Keywords:

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