- Abstract:
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A selection of new n8-permethylpentalene zirconium and hafnium complexes are reported. The first d-block metal bis(permethylpentalene) sandwich complexes, (Pn∗2M; Pn∗ = C8Me6; M = Zr, Hf) have been synthesized and structurally characterized. The bis-allyl species Pn∗M(C3H5)2 (M = Zr, Hf) have been synthesized; these complexes are fluxional in solution and react with CO2 to give the double-insertion product Pn∗M(2-O2CCH2CHCH2)2 (M = Zr, Hf). We also report monometallic, bimetallic, and polymer...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted manuscript
- Files:
-
-
(pdf, 2.3MB)
-
- Publisher copy:
- 10.1021/acs.organomet.6b00301
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Organometallics Journal website
- Volume:
- 35
- Issue:
- 12
- Pages:
- 2092-2100
- Publication date:
- 2016-06-05
- Acceptance date:
- 2016-05-31
- DOI:
- EISSN:
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1520-6041
- ISSN:
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0276-7333
- Pubs id:
-
pubs:634421
- URN:
-
uri:3874fef7-5fc3-4a95-bdd4-b8166601cf0e
- UUID:
-
uuid:3874fef7-5fc3-4a95-bdd4-b8166601cf0e
- Local pid:
- pubs:634421
- Keywords:
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- Copyright © 2016 American Chemical Society
Journal article
Zirconium and hafnium permethylpentalene compounds
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