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REFINEMENT OF THE OH A2(SIGMA+)(V=0)+AR INTERMOLECULAR POTENTIAL-ENERGY SURFACE

Abstract:

Several intermolecular vibrational levels of the excited electronic state of OH-Ar correlating with OH A 2Σ+(v=0)+Ar have been characterized by laser-induced fluorescence and hole-burning experiments. The OH-Ar levels identified include the lowest intermolecular level, an intermolecular bending level with a lower degree of stretching excitation than previously observed, and intermolecular levels with two quanta of bending excitation. The intensities of electronic transitions to these levels f...

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Publication status:
Published

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Publisher copy:
10.1063/1.464411

Authors


GIANCARLO, L More by this author
CHAKRAVARTY, C More by this author
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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
98
Issue:
12
Pages:
9320-9334
Publication date:
1993-06-15
DOI:
ISSN:
0021-9606
URN:
uuid:38552426-99d3-4128-bebc-2674c0a77f0d
Source identifiers:
53012
Local pid:
pubs:53012
Language:
English

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