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The Stark effect in the predissociating Rydberg states of NO

Abstract:

A spectroscopic study of the Stark effect in the predissociating v⁺ = 0 Rydberg states of nitric oxide, (n=13-16) is reported. The states are excited by two-colour excitation via the A²Σ⁺, v=0, N=0 state in the presence of a field in the range 0-1125 Vcm⁻¹, and the excitation is observed by using (2+1) REMPI detection of nitrogen (²D) atoms formed by predissociation. The spectra recorded over a range of fields are compared with, and hsow excellent agreement with, multichannel quantum defect t...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1080/00268970802298753

Authors


More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
Engineering and Physical Sciences Research Council More from this funder
Publisher:
Taylor & Francis Publisher's website
Journal:
Molecular Physics Journal website
Volume:
106
Issue:
9-10
Pages:
1317-1330
Publication date:
2008-05-05
DOI:
EISSN:
1362-3028
ISSN:
0026-8976
URN:
uuid:38223b03-ff01-4fe4-a254-e3fd951639b1
Local pid:
ora:4347

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