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The electrode potentials of the Group I alkali metals in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

Abstract:

The redox couples M/M+ of the Group I alkali metals Lithium, Sodium, Potassium, Rubidium and Caesium have been extensively investigated in a room temperature ionic liquid (IL) and compared for the first time. Cyclic voltammetric experiments in the IL N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]) and subsequent simulation of the data has allowed the determination of the formal potential (Ef0 vs. ferrocene/ferrocenium), standard electrochemical rate constant ...

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Publication status:
Published

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Authors


Jones, SEW More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
492
Issue:
4-6
Pages:
276-280
Publication date:
2010-06-07
DOI:
ISSN:
0009-2614
URN:
uuid:38204e3d-6113-477f-9a68-3d277415e664
Source identifiers:
60595
Local pid:
pubs:60595
Language:
English

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