- Abstract:
-
The redox couples M/M+ of the Group I alkali metals Lithium, Sodium, Potassium, Rubidium and Caesium have been extensively investigated in a room temperature ionic liquid (IL) and compared for the first time. Cyclic voltammetric experiments in the IL N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]) and subsequent simulation of the data has allowed the determination of the formal potential (Ef0 vs. ferrocene/ferrocenium), standard electrochemical rate constant ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.cplett.2010.04.063
-
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- Journal:
- CHEMICAL PHYSICS LETTERS
- Volume:
- 492
- Issue:
- 4-6
- Pages:
- 276-280
- Publication date:
- 2010-06-07
- DOI:
- ISSN:
-
0009-2614
- URN:
-
uuid:38204e3d-6113-477f-9a68-3d277415e664
- Source identifiers:
-
60595
- Local pid:
- pubs:60595
- Language:
- English
- Copyright date:
- 2010
Journal article
The electrode potentials of the Group I alkali metals in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
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