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New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands

Abstract:

Several new P or As compounds containing the 2,4,6-(CF3)3C6H2 (Ar), 2,6-(CF3)2C6H3 (Ar′) and/or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised, and characterised by multinuclear NMR spectroscopy and (for all isolated compounds) elemental analysis. The crystal and molecular structures of ArPBr2 1, Ar2PCl 2, Ar″2PCl 3, Ar″2PBr 4, Ar′ Ar″ AsCl 5, Ar′ Ar″ AsBr 6 and Ar′ Ar″ AsH 7 have been determined by single-crystal X-ray diffraction. A particularly interesting feature of these structures i...

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Publication status:
Published

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Publisher copy:
10.1039/b207327g

Authors


Batsanov, AS More by this author
Cornet, SM More by this author
Dillon, KB More by this author
Hazendonk, P More by this author
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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
24
Pages:
4622-4628
Publication date:
2002
DOI:
EISSN:
1364-5447
ISSN:
1472-7773
URN:
uuid:3800e9c5-1525-49ec-84df-1ae53d71f490
Source identifiers:
117228
Local pid:
pubs:117228
Language:
English

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